Skip to main navigation menu Skip to main content Skip to site footer

Scientific Papers

Vol. 19 No. 34 (2017): Journal 34

Physicochemical approach of moisture damage susceptibility of binder-aggregate interfaces

DOI:
https://doi.org/10.15517/khdhfb67
Submitted
November 12, 2025
Published
2025-11-13

Abstract

Moisture damage is one of the most severe distresses in pavements.  Among the causes of moisture damage is the poor quality of the binder-aggregate interface formed during mixing. The weakness of the interface might be due to a poor interaction between materials, which increases the susceptibility of binder of being removed from the aggregate surface by water. In this study, the quality of the binder-aggregate interface was approached by means of surface energy measurements of several binder-aggregate combinations. Two different aggregate sources were investigated: a limestone and a gravel, which were combined with three  asphalt binders: a diatoms-modified binder, a nanosilica-modified binder and neat binder as control. The proposed combinations were evaluated by means of physicochemical indicators related to moisture damage, such as work of adhesion, work of debonding and energy ratio. It was found that the quality of the interface is highly related to the aggregate source. Furthermore, several anti-strip additives were evaluated in terms of reduction of water susceptibility of the combinations and it was observed that their efficiency is dependent on the aggregate source with which the modified binder is combined. In summary, various parameters associated to interfaces can be obtained from surface energy measurements of binders and aggregates. This technique allows the physicochemical evaluation of binders and aggregates and the information obtained might be used as criteria for appropriate selection of water-resistant materials. 

References

  1. Aguiar-Moya, J. P., Salazar-Delgado, J., Baldi-Sevilla, A., Leiva-Villacorta, F., Loría-Salazar, L. (2015). Effect of Aging on Adhesion Properties of Asphalt Mixtures with the Use of Bitumen Bond Strength and Surface Energy Measurement Tests. Trans. Res. Rec.: J. Trans. Res. Board, 2505, pp. 57-65. doi: 10.3141/2505-08
  2. Aguiar-Moya, J. P., Baldi-Sevilla, A., Salazar-Delgado, J., Pacheco-Fallas, J., Loría-Salazar, L. Reyes-Lizcano, F., Cely-Leal, N. (2016). Adhesive Properties of Asphalts and Aggregates in Tropical Climates. Int. J. Pavement. Eng., 1-10. doi: 10.1080/10298436.2016.1199884
  3. Arabani, M., & Hamedi, Gh. H. (2011). Using the Surface free energy method to evaluate the effect of polymeric aggregate treatment on moisture damage in hot-mix asphalt. J. Mater. Civ. Eng.23, 802-811. doi: 10.1061/(ASCE)MT.1943-5533.0000228
  4. Bhasin, A., Masad, E., Little, D. & Lytton, R. (2006). Limits on Adhesive Bond Energy for Improved Resistance of Hot Mix Asphalt to Moisture Damage. Trans. Res. Rec.: J. Trans. Res. Board, 1970, pp. 3-13. doi: 10.3141/1970-03
  5. Caro, S., Masad, E., Bhasin, A., & Little, D. N. (2008). Moisture susceptibility of asphalt mixtures, Part 1: mechanisms. Inter. J. Pavement Eng., 9(2), 81–98. doi: 10.1080/10298430701792128
  6. Chen, D., Little, D., Lytton, R., & Hostle, J. (2003). Moisture Damage Evaluation of Asphalt Mixture by Considering Both Moisture Diffusion and Repeated Load Conditions. Transport. Res. Rec. 1832 (03-2730), 42-49. doi:10.3141/1832-06
  7. Cho, D., & Bahia, H. U. (2007.) Effects of Aggregate Surface and Water on Rheology of Asphalt Films. Transport. Res. Rec. 1998, 10-17. doi: 10.3141/1998-02
  8. Cho, D., & Kim, K. (2010). The Mechanisms of Moisture Damage in Asphalt Pavement by Applying Chemistry Aspects. J. Civ. Eng. 14(3), 333-342. doi: 10.1007/s12205-010-0333-z
  9. Good, R. J., and van Oss, C. J., (1991). The Modern Theory of Contact Angles and the Hydrogen Bond Components of Surface Energies. Plenum Press, New York.
  10. Hefer, A., Bhasin, A., & Little, D. (2006). Bitumen Surface Characterization Using a Contact Angle Approach.J. Mater. Civ. Eng. 18, 759-767. doi: 10.1061/(ASCE)0899-1561(2006)18:6(759)
  11. Kiggundu, B. M., & Roberts, F. L. (1988). Stripping in HMA mixtures: State-of-the-art and critical review of test methods. NCAT Report No. 88-2, National Center for Asphalt Technology, Auburn University.
  12. Little, D. N., & Jones, D. R. (2002). Chemical and mechanical processes of moisture damage in hot-mix asphalt pavement. Moisture Sensitivity of Asphalt Pavement: A National Seminar, San Diego, CA, 37-70.
  13. Masad, E., Arambula, E., Ketcham, R. A., Abbas, A. R., & Martin, A. E. (2007). Nondestructive measurements of moisture transport in asphalt mixtures. J. Assoc. Asp. Pav. Tech., 76, 919-952.
  14. Nejad, M., Hamedi, Gh. H., &Azarhoosh, A. R. (2013). Use of surface free energy method to evaluate effect of hydrate lime on moisture damage in hot-mix asphalt. J. Mater. Civ. Eng. 25, 1119-1126. doi: 10.1061/(ASCE)MT.1943-5533.0000650
  15. Taylor, M. A., & Khosla, N. P. (1983). Stripping of Asphalt Pavements: State of the Art. Transportation Research Record 911.
  16. Terrel, R. L., & Shute, J. W. (1989). Summary report on water sensitivity, SHRP-A/IR-89-003. Strategic Highway Research Program, National Research Council Washington D.C.
  17. van Oss, C. J., Chaudhury, M. K., & Good, R. J. (1988). Interfacial Lifshitz-van der Waals and Polar Interactions in Macroscopic Systems. Chem. Rev., 88, 927-941. doi: 10.1021/cr00088a006

Downloads

Download data is not yet available.